Title of article :
Synthesis and characterization of a novel (μ3-oxo)tetraruthenium cluster
Author/Authors :
Teruyuki Kondo، نويسنده , , Fumiaki Tsunawaki، نويسنده , , Toshiaki Suzuki، نويسنده , , Yasuyuki Ura، نويسنده , , Kenji Wada، نويسنده , , Syuhei Yamaguchi، نويسنده , , Hideki Masuda، نويسنده , , Kenji Yoza، نويسنده , , Motoo Shiro، نويسنده , , Take-aki Mitsudo، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
A novel (μ3-oxo)tetraruthenium cluster (2) was synthesized in an isolated yield of 73% by the reaction of a zerovalent ruthenium complex, Ru(η6-cot)(η2-dmfm)2 (1) [cot = 1,3,5-cyclooctatriene, dmfm = dimethyl fumarate], with water under reflux in 1,4-dioxane for 6 h. The structure and the X-ray characterization of this novel complex 2 as well as a possible formation mechanism of 2 are disclosed.
Keywords :
Water , Self-assembly , Catalyst , Cluster , Oxo ligands , Ruthenium
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
