Title of article :
Stereoselective tricarbonylchromium migration reactions in axially chiral biaryl chromium complexes
Author/Authors :
Ken Kamikawa، نويسنده , , Kouta Nishino، نويسنده , , Tomohiro Sakamoto، نويسنده , , Shunsuke Kinoshita، نويسنده , , Hiroyuki Matsuzaka، نويسنده , , Motokazu Uemura، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2007
Abstract :
The tricarbonylchromium group in thermodynamically unstable biaryl chromium complexes with a coordinating heteroatom at the side chain stereoselectively migrated to the other arene face to release the steric repulsion.
Keywords :
Arene–chromium complex , planar chirality , Mobile chiral auxiliary , Stereoselective migration
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry