Title of article
Novel rhodium-1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene complexes as catalysts for arylation of aromatic aldehydes
Author/Authors
Ismail Ozdemir، نويسنده , , Serpil Demir، نويسنده , , Bekir Cetinkaya، نويسنده , , Engin Cetinkaya، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2005
Pages
7
From page
5849
To page
5855
Abstract
Six new rhodium-tetrahydropyrimidin-2-ylidene complexes (2a–f) have been prepared and characterized by C, H, N analysis, 1H NMR and 13C NMR. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(I)-carbene complexes, RhCl(COD)(1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene), (2a–f), to give the corresponding secondary aryl alcohols in good yields (72–96%).
Keywords
Tetrahydropyrimidin-2-ylidene , N-heterocyclic carbene , arylation , Rhodium
Journal title
Journal of Organometallic Chemistry
Serial Year
2005
Journal title
Journal of Organometallic Chemistry
Record number
1378990
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