Title of article
Synthesis and characterization of pyridine- and thiophene-based platinacyclynes
Author/Authors
Charles A. Johnson II، نويسنده , , Benjamin A. Baker، نويسنده , , Orion B. Berryman، نويسنده , , Lev N. Zakharov، نويسنده , , Matthew J. O’Connor، نويسنده , , Michael M. Haley، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
9
From page
413
To page
421
Abstract
Seven heterocyclic macrocycles, including the first platinacycles with pyridine and thiophene rings incorporated into the cyclyne system, are reported. Pt-acetylide cyclynes were assembled via tin transmetallation or amine-mediated oxidative addition with stoichiometric PtCl2(PEt3)2 and CuI. The organometallic cyclynes exhibited enhanced electronic properties compared to previously described platinabenzocyclynes.
Keywords
Platinum(II) , Acetylide , Benzocyclyne , Heterocycle , Metallacycle
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379090
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