Title of article
Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials
Author/Authors
Ayyamperumal Sakthivel، نويسنده , , Marta Abrantes، نويسنده , , Anthony S.T. Chiang ، نويسنده , , Fritz E. Kühn، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
5
From page
1007
To page
1011
Abstract
η5-Cp(COOMe)MoCl(CO)3 is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N2 adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation.
Keywords
Epoxidation , Grafting , Organometallic complex , Mesoporous materials , Molybdenum
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379164
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