Title of article
Group 15 ligand migration in the heteronuclear clusters RuOs3(μ-H)2(CO)12(EPh3) (E = P, As, Sb)
Author/Authors
Leonard Joachim Pereira، نويسنده , , Weng Kee Leong، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
4
From page
1941
To page
1944
Abstract
The monosubstituted clusters RuOs3(μ-H)2(CO)12(EPh3) (where E = P, As, Sb) exhibit isomers in which the group 15 ligand is on an Os or an Ru vertex. Evidence is presented for hydride fluxionality and EPh3 ligand migration. These processes have been examined by variable temperature NMR studies, and the kinetic parameters estimated.
Keywords
Osmium , Chemical exchange , Ligand migration , Heterometallic complexes , Group 15 ligand , Ruthenium
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379287
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