Title of article
The preparation and crystal structure of (η5-C5H5)(OC)3Mo(CH2)3C6H5
Author/Authors
Donna S. Amenta، نويسنده , , Aimee D. Morton، نويسنده , , John W. Gilje، نويسنده , , Frank T. Edelmann، نويسنده , , Axel Fischer، نويسنده , , Steffen Blaurock، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2006
Pages
4
From page
5065
To page
5068
Abstract
The reaction of View the MathML source(η5-C5H5)Mo(CO)3- with p-CH3C6H4S(O)2O(CH2)3C6H5 produces (η5-C5H5)(OC)3Mo(CH2)3C6H5. This is only the second structurally characterized organometallic species in which an aromatic moiety is separated by three or more methylene groups. The alkyl chain adopts a staggered conformation, the Mo–C(1)–C(2)–C(3)–C(4) unit is nearly coplanar, and the alkyl chain eclipses the trans-carbonyl group on Mo. NMR evidence indicates that this conformation is preserved in solution.
Keywords
Molybdenum , conformation , Phenylpropyl complex
Journal title
Journal of Organometallic Chemistry
Serial Year
2006
Journal title
Journal of Organometallic Chemistry
Record number
1379676
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