Title of article
Comment on “Residual entropy and structural disorder in glass: A two level model and a review of spatial and ensemble vs. temporal sampling” by A. Takada, R. Conradt, and P. Richet [J. Non-Cryst. Solids, 360, 13 (2013)]
Author/Authors
Gupta، نويسنده , , Prabhat K. and Kob، نويسنده , , Walter، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
2
From page
28
To page
29
Abstract
We show that, for a two level system, the non-equilibrium (glassy state) entropy and the statistical (Gibbs) entropy – as defined by Takada et al. – are mathematically equivalent and therefore the equality between these two entropies shown by Takada et al. using simulations does not imply any new physics. In addition, we point out that the free energy of a glass, in the Takada et al. treatment, becomes less than the free energy of the liquid for all temperatures below the fictive temperature of the glass, a result that is clearly unphysical.
Keywords
Fictive temperature , Thermodynamics , free energy , GLASS , configurational entropy
Journal title
Journal of Non-Crystalline Solids
Serial Year
2014
Journal title
Journal of Non-Crystalline Solids
Record number
1385013
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