R-curve behavior and micromechanisms of fracture in resin based dental restorative composites

The fracture properties and micromechanisms of fracture for two commercial dental composites, one microhybrid (Filtek™Z250) and one nanofill (Filtek™Supreme Plus), were studied by measuring fracture resistance curves ( R -curves) using pre-cracked compact-tension specimens and by conducting both unnotched and double notched four point beam bending experiments. Four point bending experiments showed about 20% higher mean flexural strength of the microhybrid composite compared to the nanofill. Rising fracture resistance was observed over ∼1 mm of crack extension for both composites, and higher overall fracture resistance was observed for the microhybrid composite. Such fracture behavior was attributed to crack deflection and crack bridging toughening mechanisms that developed with crack extension, causing the toughness to increase. Despite the lower strength and toughness of the present nanofill composite, based on micromechanics observations, large nanoparticle clusters appear to be as effective at deflecting cracks and imparting toughening as solid particles. Thus, with further microstructural refinement, it should be possible to achieve a superior combination of aesthetic and mechanical performance using the nanocluster approach for dental composites.