Title of article :
Sintering behaviour of a glass obtained from MSWI ash
Author/Authors :
Karamanov، نويسنده , , Alexander and Aloisi، نويسنده , , Mirko and Pelino، نويسنده , , Mario، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Pages :
10
From page :
1531
To page :
1540
Abstract :
The sintering behaviour of a glass obtained by Municipal Solid Waste Incinerator (MSWI) bottom ash (WG) was investigated and compared with a Na2O–MgO–CaO–SiO2 composition (CG). The sintering activation energy, Esin, and the energy of viscous flow, Eη, were evaluated by dilatomeric measurements at different heating rates. The formation of crystalline phases was evaluated by Differential Thermal Analysis (DTA) and X-Ray Diffraction (XRD), and observed by Scanning Electron Microscopy (SEM) and Transition Electron Microscopy (TEM). In CG, the sintering started at ≈1013 dPa s viscosity and Esin (245 kJ/mol) remains constant in the measured range of shrinkage, up to 9%. In WG the densification started at ≈1011 dPa s, Esin resulted to be 395 kJ/mol up to 5% shrinkage, 420 kJ/mol at 8% and 485 kJ/mol at 10% shrinkage. The sintering rate decreased due to the beginning of the pyroxene formation and the densification stopped in the temperature range 1073–1123 K after formation of 5 ± 3% and 13 ± 3% crystal phase, at 5 and 20 K/min, respectively. Higher densification and improved mechanical properties were obtained by applying the fast heating rate, i.e. 20 K/min.
Keywords :
Glass-ceramics , Industrial wastes , waste materials , Sinter-crystallization
Journal title :
Journal of the European Ceramic Society
Serial Year :
2005
Journal title :
Journal of the European Ceramic Society
Record number :
1407588
Link To Document :
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