Tribological properties of a perfluoropolyether lubricant with 3-phenylpropyl functional group for hard disk media

A new perfluoropolyether lubricant (LUB-A) with a 3-phenylpropyl functional group at both ends of the main chain was designed and synthesized by the authors for use in hard disk media, and its tribological performance was evaluated. Time-of-flight secondary ion mass spectrometry showed that LUB-A film on the disk lost none of its functional groups even after a 672 h exposure at 23 °C and 55% RH, although AM3001 lost 94% of its (3,4-dioxomethylenephenyl)methyl functional groups after the same period of exposure. It was found that cyclotriphosphazene (X-1P) was more than four times more soluble in 2 nm thick LUB-A film than in AM3001 film. The degradation ratio of read-back signals in the seek test was less than 5% over a wide range of X-1P content in LUB-A film and no micro-phase separation was induced, in contrast to AM3001 film that could not keep the degradation ratio at less than 5% without inducing micro-phase separation. LUB-A also showed better migration properties at 80 °C and 3% RH than AM3001. LUB-A was proved to be more chemically stable and to show better tribological performance than the currently popular AM3001 when it was used as a thin film mixed with X-1P.