Development of amorphous carbon coating with luminescent silica/CdSe/ZnS quantum dots underlayer for wear monitoring

Amorphous carbon (a-C) coating with luminescent wear-sensing underlayer is developed for achieving the tribological coating with wear monitoring capability. Wear monitoring of a-C coating by luminescent spectroscopy to determine the remaining thickness of the coating after the wear test is also demonstrated. The coating structure consists of a-C films deposited by R.F. magnetron sputtering method onto the luminescent layer, which is made from silica coating containing CdSe/ZnS quantum dots (Silica/QD). A thin Si-intermediate layer is added between a-C and silica/QD layer for adhesion improvement. The physical as well as tribological properties of the coatings are analysed. Furthermore, wear monitoring of a-C films is also demonstrated to determine the remaining coating thickness after the tribological test. The demonstration is carried out by firstly formulating a relation between luminescent intensity detected from the coating and coating thickness. Then the luminescent intensity is measured again from the wear track. The remaining thickness is finally determined by using the relationship between luminescent intensity and coating thickness. The fabricated coating exhibits a smooth surface with the average surface roughness of 1.35 nm and a friction coefficient of 0.1. The demonstration of wear monitoring shows that the remaining thickness of the coating after the tribological test determined by luminescent spectroscopy is compared well with the thickness measured by profilometry. This suggests that wear monitoring of a-C films by luminescent spectroscopy technique is feasible.