Title of article
First gravimetric detection of ethene utilizing metallo-supramolecular macrocycles as sensor-active substances
Author/Authors
Graewe، نويسنده , , Boris and Rang، نويسنده , , Alexander and Schalley، نويسنده , , Christoph A. and Haubrich، نويسنده , , Jan and Bargon، نويسنده , , Joachim، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
6
From page
302
To page
307
Abstract
For the first time, the real-time gravimetric detection of the light-weight analyte ethene with quartz microbalance sensors becomes possible in the range of 3–600 ppm, when metallo-supramolecular macrocycles are used as sensor-active layers. Thermodynamic and kinetic measurements as well as theoretical simulations indicate a weak and reversible binding of ethene at the metal centers.
Keywords
Sensoractive layers , Pt and Pd 16-electron-complexes , Quartz microbalance , Ethene , RI-DFT-calculations
Journal title
Sensors and Actuators B: Chemical
Serial Year
2006
Journal title
Sensors and Actuators B: Chemical
Record number
1438511
Link To Document