Suitable properties of ink to create inkjet-printed surface-directed microchannels that utilize the pinning effect of a triple line on a rough surface

If microfluidic devices can be directly produced using printing techniques, the combination of microfluidics and printing techniques for other applications, such as printed electronics, will make all-printed highly-functionalized microfluidic devices possible. Therefore, we have made efforts to develop a technique for producing microfluidic devices using an inkjet printer. The microchannels that could be created using this technique were a kind of surface-directed channels that utilize the pinning effect of a triple line on a rough surface. In this study, we focused on what were the required properties of the printer ink during the wetting and drying processes of the ink. As a result, one of the properties required during the wetting process was that the advancing contact angle of the ink should be smaller than a certain value, which depended on the average volume of the ink drops ejected from the printhead and the number of drops per unit area. The receding contact angle should be smaller than about one third of each advancing angle. In addition, during the drying process, a small amount of surfactant added to the ink played a critical role in order to leave a continuous stain of the ink. As an application of this inkjet-printed channel, we also created a device for mixing aqueous solutions.