• Title of article

    Application of liquid chromatography–electrospray ionization mass spectrometry for study of steroid-converting enzymes

  • Author/Authors

    Mik??́k، نويسنده , , Ivan and Mikul?́kov?، نويسنده , , Kate?ina and P?cha، نويسنده , , Ji??́ and Ku?ka، نويسنده , , Marek and Deyl، نويسنده , , Zden?k، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    9
  • From page
    145
  • To page
    153
  • Abstract
    A high-performance liquid chromatography–atmospheric pressure ionization–electrospray ionization mass spectrometry (HPLC–API–ESI–MS) method was developed for the analysis of steroids in a study of steroid-converting enzymes. Separations ware done on a Zorbax Eclipse XDB-C18 column (eluted with a linear methanol–water–acetic acid gradient) and identification of the steroids involved was done by API–ESI–MS using positive ion mode and extracted ion analysis. The applicability of the present method for studying steroid metabolism was proven in assaying two steroid-converting enzymes (20β-hydroxysteroid dehydrogenase and 11β-hydroxysteroid dehydrogenase) in various biological samples (rat and chicken intestine, chicken oviduct).
  • Keywords
    enzymes , Steroids , steroid-converting
  • Journal title
    Journal of Chromatography B
  • Serial Year
    2004
  • Journal title
    Journal of Chromatography B
  • Record number

    1456417