Title of article :
Synthesis of 1,4-benzodiazepinones via palladium-catalysed allene carbopalladation/amination domino sequence
Author/Authors :
Rigamonti، نويسنده , , Micol and Prestat، نويسنده , , Guillaume and Broggini، نويسنده , , Gianluigi and Poli، نويسنده , , Giovanni، نويسنده ,
Issue Information :
دوفصلنامه با شماره پیاپی سال 2014
Abstract :
Vinyl-substituted 1,4-benzodiazepinones were obtained in good yields (10 examples, 61–82% yield) via the reaction between N-allenyl anthranyl amides and aryl iodides under Pd(0) catalysis. This new single cycle catalytic domino transformation involves a C–C followed by an N–C bond formation.
Keywords :
amination , 1 , 4-Benzodiazepinones , Allene , domino reactions , PALLADIUM , Carbopalladation
Journal title :
Journal of Organometallic Chemistry
Journal title :
Journal of Organometallic Chemistry
