Title of article
New ionic fluorenylnickel complexes: Synthesis and solid state structure
Author/Authors
Kozio?، نويسنده , , Andrzej and Jerzykiewicz، نويسنده , , Lucjan B. and Justyniak، نويسنده , , Iwona and Lis، نويسنده , , Tadeusz and Pasynkiewicz، نويسنده , , Stanis?aw and Pietrzykowski، نويسنده , , Antoni، نويسنده ,
Issue Information
دوفصلنامه با شماره پیاپی سال 2014
Pages
5
From page
22
To page
26
Abstract
New fluorenylnickel complexes [M(THF)n]+[Ni(η5-Flu)(η1-Flu)2]− (M = +48 Li, 1 and M = Na, 2) have been obtained in the reaction of nickel bromide with fluorenyllithium and -sodium. The X-ray molecular structures of 1 (monoclinic; P21/c) and 2 (orthorhombic; Fdd2) reveal that in both complexes two fluorenyl ligands are bonded to the nickel atom by η1 bond and the third one is bonded to the nickel atom by η5 bond. Complexes 1 and 2 are the first structurally characterized nickel complexes bearing fluorenyl ligands.
Keywords
nickel , Fluorene , crystal structure determination
Journal title
Journal of Organometallic Chemistry
Serial Year
2014
Journal title
Journal of Organometallic Chemistry
Record number
1458863
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