Investigation of Ag-bulk/glassy-phase/Si heterostructures of printed Ag contacts on crystalline Si solar cells

The interface structure of screen-printed silver contacts on a crystalline silicon solar cell has been studied by transmission electron microscopy (TEM). TEM results confirmed that the glassy-phase plays an important role in contact properties. There are at least three different microstructures present in optimal fired contacts. The location where silver-bulk directly contacts silicon is observed through SEM, and this is actually a very thin glass layer in between. In addition, high-density silver embryos on silicon were found for samples fired optimally. The results presented in this study suggest that Ag-bulk/thin-glass-layer/Si contact is the most decisive path for current transportation.