2D device modelling and finite element simulations for thin-film solar cells

Thin-film heterojunction solar cell devices are modelled in two dimensions, from fundamental material parameters, using the finite element method. The electrostatic potential is solved for, together with the quasi-Fermi levels, while optical absorption is calculated from n and k values of the materials used. s implementation, all material parameters can be input as functions of spatial coordinates, which makes it very flexible when applied to materials with inhomogeneities. As an example of the model in use, it is applied to a thin-film solar cell based on a structure with a CIGS absorber layer, a CdS buffer layer and a ZnO/ZAO transparent front contact. The effects of spatial inhomogeneities in the band gap energy and in the mid-gap trap level density on device performance are simulated.