Thermogravimetric analysis and kinetics of coal/plastic blends during co-pyrolysis in nitrogen atmosphere

Investigations into the co-pyrolytic behaviours of different plastics (high density polyethylene, low density polyethylene and polypropylene), low volatile coal and their blends with the addition of the plastic of 5 wt.% have been conducted using a thermogravimetric analyzer. The results indicated that plastic was decomposed in the temperature range 438–521 °C, while the thermal degradation temperature of coal was 174–710 °C. The overlapping degradation temperature interval between coal and plastic was favorable for hydrogen transfer from plastic to coal. The difference of weight loss (▵W) between experimental and theoretical ones, calculated as an algebraic sum of those from each separated component, was 2.0–2.7% at 550–650 °C. These experimental results indicated a synergistic effect during plastic and coal co-pyrolysis at the high temperature region. In addition, a kinetic analysis was performed to fit thermogavimetric data, the estimated kinetic parameters (activation energies and pre-exponential factors) for coal, plastic and their blends, were found to be in the range of 35.7–572.8 kJ/mol and 27–1.7 × 1038 min− 1, respectively.