Solubility and surface thermodynamics of conducting polymers by inverse gas chromatography. III: Polypyrrole chloride

Inverse gas chromatography, IGC, was applied to characterize conducting polypyrrole chloride (PPyCl) using twenty three solvents. IGC is able to reveal the change in the morphology, the strength of solvent–PPyCl interactions, thermodynamics parameters (χ12, Ω 1 ∞ ), solvent and polymer solubility parameters, and molar heats of sorption, mixing and evaporation ( Δ H 1 s , Δ H 1 ∞ , Δ H 1 v ). The following solvents showed stronger interactions than others; yet, none of these solvents are good solvents for PPyCl: dodecane among the alkane family, tetrahydrofuran and methyl ethyl ketone among the oxy and keto group, dichloromethane among the chlorinated group up to 120 °C and chloroform at 180 °C, and toluene among the cyclic and aromatic group. Overall, the groups showed higher affinities to PPyCl are: acetates, oxy and cyclic, and chlorinated groups. Comprehensive solvents and PPyCl solubility parameters are obtained. The latter showed that PPyCl is not soluble in any solvent used.