Estimation of the particle–wall interaction energy in sedimentation field flow fractionation

A new sedimentation field flow fractionation (SdFFF) method is presented for the estimation of the total potential energy of interaction between colloidal particles and the channel wall. The method is based on the variation of the mean cloud thickness in SdFFF due to the variation of the suspensionʹs ionic strength. It requires only two SdFFF experiments at two different ionic strengths and at a constant acceleration field. The found values are compatible with those calculated from the various forms of equations of the Derjaguin–Landau–Verwey–Overbeek (DLVO) theory.