Title of article :
On a quantitative scale for Lewis acidity and recent progress in polynitrogen chemistry
Author/Authors :
Christe، نويسنده , , Karl O and Dixon، نويسنده , , David A and McLemore، نويسنده , , Douglas and Wilson، نويسنده , , William W and Sheehy، نويسنده , , Jeffrey A and Boatz، نويسنده , , Jerry A، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
A quantitative scale for Lewis acidities based on fluoride ion affinities is discussed. It uses pF− values which represent the fluoride ion affinities in kcal/mol divided by 10. These values were obtained for 106 Lewis acids in a self-consistent manner using ab initio calculations at the MP2/PDZ level of theory. In the area of polynitrogen chemistry, the synthesis and characterization of the novel N5+ cation from N2F+ and HN3 is described.
Keywords :
Polynitrogen compounds , High energy density materials , Fluoride affinity calculations , Ab initio calculations , Synthesis , Lewis acidity scale
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
