Title of article :
Preparation of 3-trifluoromethyl-2-cycloalkenones by the oxidative rearrangement of trifluoromethylated tertiary allylic alcohols with pyridinium chlorochromate
Author/Authors :
Prakash، نويسنده , , G.K.Surya and Tongco، نويسنده , , Emily C. and Mathew، نويسنده , , Thomas and Vankar، نويسنده , , Yashwant D. and Olah، نويسنده , , George A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
Trifluoromethylated tertiary allylic alcohols, obtained from trifluoromethylation of several conjugated enones, undergo oxidative rearrangements to 3-trifluoromethyl-2-cycloalkenones with pyridinium chlorochromate in the presence of a small amount of concentrated H2SO4.
Keywords :
Trifluoromethyltrimethylsilane , Trifluoromethylated tertiary allylic alcohols , Pyridinium chlorochromate , 3-trifluoromethyl-2-cycloalkenones
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
