Title of article
Perfluoroalkylation of aliphatic thiols in the presence of sodium hydroxymethanesulfinate
Author/Authors
Anselmi، نويسنده , , Elsa and Blazejewski، نويسنده , , Jean-Claude and Tordeux، نويسنده , , Marc and Wakselman، نويسنده , , Claude، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
41
To page
44
Abstract
Direct perfluoroalkylation of aliphatic thiols was performed in the presence of sodium hydroxymethanesulfinate (Rongalite). Reaction of mercaptoalkanoic esters with trifluoromethyl bromide gave the corresponding trifluoromethylthio ethers. Condensation of alkane dithiols with perfluoroalkyl iodides led mainly to fluorinated dithioethers. These alkylation reactions are interpreted as occurring via in situ formation of dialkyldisulfides.
Keywords
Hydroxymethanesulfinate , Perfluoroalkyl sulfides , thiols , Trifluoromethyl bromide , disulfides
Journal title
Journal of Fluorine Chemistry
Serial Year
2000
Journal title
Journal of Fluorine Chemistry
Record number
1602944
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