Title of article
Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine
Author/Authors
Quan، نويسنده , , Heng-dao and Tamura، نويسنده , , Masanori and Murata، نويسنده , , Junji and Gao، نويسنده , , Ren-xiao and Sekiya، نويسنده , , Akira، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
5
From page
121
To page
125
Abstract
A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.
Keywords
1 , 2 , 2-tetrafluoroethylether , 2-chloro-1 , Porous aluminium fluoride , fluorination , Ethyl 1 , 2-trifluoroethylmethylether , 1
Journal title
Journal of Fluorine Chemistry
Serial Year
2000
Journal title
Journal of Fluorine Chemistry
Record number
1603008
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