Title of article :
Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride
Author/Authors :
Sekiya، نويسنده , , Akira and Quan، نويسنده , , Heng-dao and Tamura، نويسنده , , Masanori and Gao، نويسنده , , Ren-Xiao and Murata، نويسنده , , Junji، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.
Keywords :
Porous aluminum fluoride , 2-trifluoro-2-methoxyethane , 1 , 1 , 2-chloro-1 , 1 , 2-tetrafluoro-2-methoxyethane , Methyl chlorodifluoroacetate , 2 , 2-dichloro-1
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
