Title of article :
Reactions of oxalyl fluoride with electrophiles
Author/Authors :
Murata، نويسنده , , Junji and Tamura، نويسنده , , Masanori and Sekiya، نويسنده , , Akira، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
The reactions of oxalyl fluoride with electrophiles in the presence of alkali metal fluoride were carried out. In the reaction with CF3CH2OTf (Tf=CF3SO2) or CH3CH2OTf, the synthesis of di-ether (ROCF2CF2OR) and mono-ether (ROCF2COF) was achieved. The difference of the reactivities between these two compounds was discussed from the result of DFT calculations.
Keywords :
2-bis(2 , Cesium fluoride , 2-trifluoroethoxy)-1 , 2 , Oxalyl fluoride , 1 , 2-Tetrafluoroethane , 2 , DFT calculation , 1
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
