Title of article
Bismuth(III) bis(trifluoromethanesulfonyl)amide
Author/Authors
Picot، نويسنده , , Alexandre and Répichet، نويسنده , , Sigrid and Roux، نويسنده , , Christophe Le and Dubac، نويسنده , , Jacques and Roques، نويسنده , , Nicolas، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
6
From page
129
To page
134
Abstract
Bismuth(III) bis(trifluoromethanesulfonyl)amide (Bi(NTf2)3, 3) has been prepared from the reaction of protiodemetallation of tri-p-tolylbismuth by a stoichiometric amount of bis(trifluoromethanesulfonyl)amine (1). The intermediates BiPh3−n(NTf2)n (n=2 (4), 1 (5)) resulting from the reaction of 1 with triphenylbismuth have also been isolated. The amide 3 was able to catalyze the benzoylation and the benzenesulfonylation of toluene.
Keywords
Tri-p-tolylbismuth , Bis(trifluoromethanesulfonyl)amine , Bismuth bis(trifluoromethanesulfonyl)amides , Methylbenzophenone , Methyldiphenyl sulfone , Triphenylbismuth
Journal title
Journal of Fluorine Chemistry
Serial Year
2002
Journal title
Journal of Fluorine Chemistry
Record number
1603621
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