Title of article :
Solvolyis reactions of perfluoro-5-aza-4-nonene, C3F7CFNC4F9
Author/Authors :
Siedle، نويسنده , , A.R. and Webb، نويسنده , , Robert J and Newmark، نويسنده , , R.A and Brostrom، نويسنده , , Myles and Weil، نويسنده , , David A and Erickson، نويسنده , , Kristin and Behr، نويسنده , , Fred.E and Young Jr.، نويسنده , , Victor G، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Pages :
8
From page :
175
To page :
182
Abstract :
Hydrolysis of the imine perfluoro-5-aza-4-nonene, C3F7CFNC4F9, in ether was studied by several spectroscopic techniques including 17O NMR. The initial product is C3F7CONHC4F9 which is converted to (C3F7CO)2NH and then to C3F7CONH2 and C3F7CO2H. Solvolysis in liquid ammonia afforded the amidine C3F7C(NH)NH2. Reaction with hydrazine produced 3,5-bis(heptafluoropropyl)-1,2,4-triazole whose crystal structure is reported.
Keywords :
4-Triazole , Heptafluorobutyramide , 17O NMR , Heptafluorobutyrimide , Perfluoro-5-aza-4-nonene , 3 , 5-bis(Heptafluoropropyl)-1 , Solvolysis , 2
Journal title :
Journal of Fluorine Chemistry
Serial Year :
2003
Journal title :
Journal of Fluorine Chemistry
Record number :
1607640
Link To Document :
https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1607640
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