Title of article
2,4-Bridged 1,5-bis(fluoroalkyl)-1,3,5-triketones: synthesis and properties
Author/Authors
Chizhov، نويسنده , , D.L. and Pashkevich، نويسنده , , K.I. and Rِschenthaler، نويسنده , , G.-V.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
6
From page
267
To page
272
Abstract
Symmetrical and unsymmetrical bis-fluoroacylcyclopentanones and cyclohexanones were synthesized. NMR data reveal that the keto–enol tautomeric equilibrium is changed markedly by the presence of a trimethylene bridge compared to an ethylene moiety. A considerable influence of the fluoroalkyl chain length was found for 2,6-(bisfluoroacyl)cyclohexanones.
Keywords
Fluorinated 1 , 3 , Cycloalkanones , Polyfluoroalkyl groups , Keto–enol equilibrium , 5-Triketones
Journal title
Journal of Fluorine Chemistry
Serial Year
2003
Journal title
Journal of Fluorine Chemistry
Record number
1607800
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