Title of article
Fluoride-assisted trifluoromethylation of aromatic thiones with (trifluoromethyl)trimethylsilane
Author/Authors
Large-Radix، نويسنده , , Sylvie and Billard، نويسنده , , Thierry and Langlois، نويسنده , , Bernard R، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
3
From page
147
To page
149
Abstract
In the presence of a stoichiometric amount of Bu4NF·3H2O, (trifluoromethyl)trimethylsilane reacts with aromatic thiones in both thiophilic and carbophilic ways to deliver, in medium yield, a mixture of (trifluoromethylthio)diarylmethane and 1,1-diaryl-2,2,2-trifluoroethanethiol, the former product being the major one.
Keywords
trifluoromethylation , (Trifluoromethyl)trimethylsilane , Trifluoromethyl sulfides , ?-(Trifluoromethyl)thiols
Journal title
Journal of Fluorine Chemistry
Serial Year
2003
Journal title
Journal of Fluorine Chemistry
Record number
1607881
Link To Document