Title of article
Fluorocarbon oxy and peroxy radicals
Author/Authors
von Ahsen، نويسنده , , Stefan and Willner، نويسنده , , Helge and Argüello، نويسنده , , Gustavo A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
14
From page
1057
To page
1070
Abstract
This review deals with the most fundamental fluorocarbon oxy (x=1) and peroxy (x=2) radicals CF3Ox, FC(O)Ox, CF3C(O)Ox and CF3OC(O)Ox. Their role in atmospheric and synthetic chemistry is described as well as their formation and characterisation in the gas phase and isolated in low temperature matrices. Reservoirs and hence thermal sources for oxy and peroxy radicals are peroxides (ROOR) and peroxynitrates (ROONO2), while catenated trioxides (ROOOR) are precursors for both oxy and peroxy radicals simultaneously. The synthesis and some properties of these precursors are also described.
Keywords
atmospheric chemistry , Trioxides , Peroxynitrates , Matrix spectroscopy , Peroxides , radicals
Journal title
Journal of Fluorine Chemistry
Serial Year
2004
Journal title
Journal of Fluorine Chemistry
Record number
1608294
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