Title of article
NMR spectroscopic study of xenon fluorides in the gas phase and of XeF2 in the solid state
Author/Authors
Gerken، نويسنده , , Michael and Hazendonk، نويسنده , , Paul and Nieboer، نويسنده , , Jared and Schrobilgen، نويسنده , , Gary J.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
6
From page
1163
To page
1168
Abstract
The xenon fluorides, XeF2, XeF4, and XeF6, were characterized by gas-phase 129Xe and 19F NMR spectroscopy, providing the first gas-phase NMR spectroscopic data for the xenon fluorides. Xenon difluoride was also characterized in the solid state by static and magic angle spinning (MAS) 129Xe and 19F NMR spectroscopy, providing experimental values for the 129Xe (4260±10 ppm) and 19F (125±5 ppm) shielding anisotropies in XeF2. A method for encapsulating reactive fluoride samples for study by MAS NMR spectroscopy is also described.
Keywords
fluorine , Gas-phase NMR spectroscopy , Shielding anisotropy , Solid-state NMR spectroscopy , Xenon
Journal title
Journal of Fluorine Chemistry
Serial Year
2004
Journal title
Journal of Fluorine Chemistry
Record number
1608346
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