Title of article
Fluoroalkenylphosphonates from branched chain and cyclic perfluoroolefins
Author/Authors
Kadyrov، نويسنده , , Alexander A. and Silaev، نويسنده , , Dmitry V. and Makarov، نويسنده , , Kiril N. and Gervits، نويسنده , , Lev L. and Rِschenthaler، نويسنده , , Gerd-Volker، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
1407
To page
1410
Abstract
In a Arbuzov-type reaction branched chain and cyclic perfluoroolefins react with trimethylsilyl diethyl phosphite to give new fluorinated alkenylphosphonates. Two internal olefins furnish by a radical addition of dialkyl phosphites fluoroalkylphosphonates, which could be converted using BF3·NEt3 to give the respective fluoroalkenylphosphonates.
Keywords
Fluorine substitution , radical addition , Perfluorinated olefins , Dialkylphosphites , Trialkylphosphites , Fluorinated phosphonates
Journal title
Journal of Fluorine Chemistry
Serial Year
2004
Journal title
Journal of Fluorine Chemistry
Record number
1608450
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