Author/Authors :
Dolbier Jr.، نويسنده , , William R. and Aït-Mohand، نويسنده , , Samia and Schertz، نويسنده , , Tyler D. and Sergeeva، نويسنده , , Tatiana A. and Cradlebaugh، نويسنده , , Joseph A. and Mitani، نويسنده , , Akira and Gard، نويسنده , , Gary L. and Winter، نويسنده , , Rolf W. and Thrasher، نويسنده , , Joseph S.، نويسنده ,
Abstract :
Both SF5Cl and SF5Br undergo smooth, high yield addition to alkenes and alkynes under the mild free radical chain reaction conditions of triethylborane initiation at low temperature, although the SF5Br chemistry is somewhat limited by its competing high electrophilic reactivity with electron rich alkenes. The SF5Cl addition reaction is relatively insensitive to a wide variety of non-allylic functionalities.
Keywords :
Pentafluorosulfanyl substituent , Free radical chain reaction , SF5Cl , Triethylborane initiation , SF5Br
