Title of article :
A new method for the synthesis of trifluoromethylating agents—Diaryltrifluoromethylsulfonium salts
Author/Authors :
Yagupolskii، نويسنده , , Lev M. and Matsnev، نويسنده , , Andrej V. and Orlova، نويسنده , , Raisa K. and Deryabkin، نويسنده , , Boris G. and Yagupolskii، نويسنده , , Yurii L.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
A new synthetic method has been developed to prepare diaryltrifluoromethylsulfonium salts from diaryldifluorosulfuranes by the action of Me3SiCF3/F−. This reaction is the transformation of nucleophilic trifluoro-methylating reagent into electrophilic one.
Keywords :
Diaryltrifluoromethylsulphonium salts , Diarylsulfides , Nucleophilic mechanism , Trifluoromethyl group
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
