Author/Authors :
Miroslav S Leskiv، نويسنده , , Miroslav S. and Chilingarov، نويسنده , , Norbert S. and Rau، نويسنده , , Julietta V. and Ferro، نويسنده , , Daniela and Abramov، نويسنده , , Sergey V. and Spiridonov، نويسنده , , Felix M. and Sidorov، نويسنده , , Lev N.، نويسنده ,
Abstract :
The thermal decomposition of cobalt trifluoride was studied by High Temperature Mass Spectrometry (HTMS). It was ascertained that the rate of atomic fluorine evolution in the gas phase might be increased by adding small amounts of Ni(s) or CoF2(s) to cobalt trifluoride. Scanning Electron Microscopy combined with Energy Dispersive X-ray spectroscopy (SEM/EDX) was used to determine the morphology and composition of the solid product surface layer formed under different rates of CoF3(s) thermolysis.
Keywords :
mass spectrometry , Atomic and molecular fluorine , Thermal decomposition of solids , Thermolysis of solid fluorinating reagents , Solid-phase fluorination
