Title of article
Asymmetric intramolecular Cannizzaro reaction of anhydrous phenylglyoxal
Author/Authors
Ishihara، نويسنده , , Kazuaki and Yano، نويسنده , , Takayuki and Fushimi، نويسنده , , Makoto، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
994
To page
997
Abstract
The use of anhydrous phenylglyoxal provides a solution to the problem of low reactivity in the asymmetric intramolecular Cannizzaro reaction with alcohols. Double asymmetric induction was achieved in the reaction of anhydrous phenylglyoxal with d-(+)-menthol promoted by a (S,S)-t-BuBox·copper(II) hexafluoroantimonate complex.
Keywords
Double asymmetric induction , Anhydrous , Phenylglyoxal , Bis(oxazoline) , Copper(II) hexafluoroantimonate , Intramolecular Cannizzaro reaction
Journal title
Journal of Fluorine Chemistry
Serial Year
2008
Journal title
Journal of Fluorine Chemistry
Record number
1610267
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