Title of article
The reaction of SF5Br with select 1,2-dihaloethylenes
Author/Authors
Winter، نويسنده , , Rolf Walter and Gard، نويسنده , , Gary L.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
1041
To page
1043
Abstract
SF5Br reacts with 1,2-haloethylenes (F, Cl, Br) in distinct ways. In the case of F- and Cl-olefins, the expected addition occurs while with 1,2-dibromoethylene a metathetical reaction yielding in a clean reaction a 1:1 mixture of SF5CHCHBr and CHBr2CHBr2 is found. The mechanism for this reaction is discussed.
Keywords
SF5-alkyl halides (Br , SF5-addition , Cl) , Substitution , Exchange
Journal title
Journal of Fluorine Chemistry
Serial Year
2008
Journal title
Journal of Fluorine Chemistry
Record number
1610282
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