Title of article :
Novel ring-cleaving reaction of 4-nitro-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane with nucleophiles
Author/Authors :
Dolbier Jr.، نويسنده , , William R. and Zhai، نويسنده , , Yian and Xu، نويسنده , , Wei and Wheelus، نويسنده , , Will and Dulong، نويسنده , , Florian and Goldberg، نويسنده , , Efram and Ghiviriga، نويسنده , , Ion and Battiste، نويسنده , , Merle A.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2008
Abstract :
When 4-nitro-AF4 is treated with nucleophiles such as alkoxides and cyanide, a novel ring opening, cyclophane destroying reaction is observed whereby, via an SNAr mechanism, the nucleophile attacks the bridgehead aryl carbon vicinal to the nitro group with subsequent aryl-CF2 bond cleavage.
Keywords :
AF4 , nucleophilic substitution , Fluorine reactivity effects
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
