Title of article
Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide
Author/Authors
Kino، نويسنده , , Tatsuhito and Nagase، نويسنده , , Yu and Ohtsuka، نويسنده , , Yuhki and Yamamoto، نويسنده , , Kyoko and Uraguchi، نويسنده , , Daisuke and Tokuhisa، نويسنده , , Kenji and Yamakawa، نويسنده , , Tetsu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
8
From page
98
To page
105
Abstract
Trifluoromethylation of aromatic and hetero-aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide was investigated. Various trifluoromethylated benzene derivatives, six-membered nitrogen-containing aromatic compounds and five-membered hetero-aromatic compounds were obtained under mild conditions. General orientation of electrophilic substitution of aromatic compounds was observed similarly as reported in other radical trifluoromethylation previously.
Keywords
trifluoromethylation , Trifluoromethyl radical , Trifluoromethyl iodide
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1610767
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