Title of article
2-Fluoro-3-phenyl-allyltrimethylsilane: A new fluorinated reagent for Hosomi–Sakurai reaction
Author/Authors
Hayashi، نويسنده , , Tsuyoshi and Usuki، نويسنده , , Yoshinosuke and Iio، نويسنده , , Hideo، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
5
From page
709
To page
713
Abstract
2-Fluoro-3-phenyl-allyltrimethylsilane, prepared from β-fluorinated allylic acetate via a π-allylpalladium intermediate, reacted with various aldehydes and acetals in the presence of TiCl4 to afford the corresponding homoallyl alcohols and homoallyl ethers, respectively, in good to moderate yields.
Keywords
Hosomi–Sakurai reaction , ?-Fluorinated allylsilane , Lewis acid-promoted allylation
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1610943
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