Title of article
Determination of pKa values of fluoroalkanesulfonamides and investigation of their nucleophilicity
Author/Authors
Zhang، نويسنده , , Cheng-Pan and Wang، نويسنده , , Zong-Ling and Chen، نويسنده , , Qingyun and Zhang، نويسنده , , Chun-Tao and Gu، نويسنده , , Yu-Cheng and Xiao، نويسنده , , Ji-Chang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
6
From page
761
To page
766
Abstract
The pKa values of a series of fluoroalkanesulfonylamides were measured by potentiometric titration. Different kinds of alkyl halides and tosylates were employed to investigate the nucleophilicity of fluoroalkanesulfonylamides. Fluoroalkanesulfonylamides with longer fluoroalkyl chain have weaker nucleophilicity.
Keywords
pKa values , Fluoroalkanesulfonamides , nucleophilicity , Substitution , Alkylation , nucleophiles
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1610960
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