Title of article
Decarboxylative trifluoromethylation of aryl halides using well-defined copper–trifluoroacetate and –chlorodifluoroacetate precursors
Author/Authors
McReynolds، نويسنده , , Kristen A. and Lewis، نويسنده , , Robert S. and Ackerman، نويسنده , , Laura K.G. and Dubinina، نويسنده , , Galyna G. and Brennessel، نويسنده , , William W. and Vicic، نويسنده , , David A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
5
From page
1108
To page
1112
Abstract
New synthetic routes to (NHC)copper–trifluoroacetate and –chlorodifluoroacetate complexes were developed (NHC = N-heterocyclic carbenes) so baseline reactivity patterns could be established for the decarboxylative trifluoromethylation of organic halides. In the presence of aryl halides, loss of CO2 from these new precursors occurred at 160 °C concurrent with the formation of aryl–CF3.
Keywords
trifluoromethylation , Copper , Organometallic
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1611061
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