Title of article
High-temperature and photochemical syntheses of C60 and C70 fullerene derivatives with linear perfluoroalkyl chains
Author/Authors
Shustova، نويسنده , , Natalia B. and Kareev، نويسنده , , Ivan E. and Kuvychko، نويسنده , , Igor V. and Whitaker، نويسنده , , James B. and Lebedkin، نويسنده , , Sergey F. and Popov، نويسنده , , Alexey A. and Dunsch، نويسنده , , Lothar and Chen، نويسنده , , Yu-Sheng and Seppelt، نويسنده , , Konrad and Strauss، نويسنده , , Steven H. and Boltalina، نويسنده , , Olga V.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
15
From page
1198
To page
1212
Abstract
New experimental results on perfluoroalkylation of C60 and C70 with the use of RfI (Rf = CF3, C2F5, n-C3F7, n-C4F9, and n-C6F13), along with a critical overview of the existing synthetic methods, are presented. For the selected new fullerene (Rf)n compounds we report spectroscopic, electrochemical and structural data, including improved crystallographic data for the isomers of C70(C2F5)10 and C60(C2F5)10, and the first X-ray structural data for the dodecasubstituted perfluoethylated C70 fullerene, C70(C2F5)12, which possesses unprecedented addition pattern.
Keywords
Fullerene , C60 , C70 , Perfluoroalkylation , Perfluoroalkyl iodide , Electrochemistry , Flow reactor , Sealed ampules , Thermal heating
Journal title
Journal of Fluorine Chemistry
Serial Year
2010
Journal title
Journal of Fluorine Chemistry
Record number
1611086
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