Title of article :
Trialkyl borate assisted amination of fluorinated 1,3-diketones for synthesis of N,N′-1,2-phenylen-bis(β-aminoenones) and their Ni(II), Cu(II) and Pd(II) complexes
Author/Authors :
Chizhov، نويسنده , , Dmitrii L. and Pervova، نويسنده , , Marina G. and Samorukova، نويسنده , , Mariya A. and Khmara، نويسنده , , Ekaterina F. and Filyakova، نويسنده , , Vera I. and Saloutin، نويسنده , , Viktor I. and Charushin، نويسنده , , Valery N.، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
An effecient synthetic method for fluorinated tridentate β-aminoenones and tetradentate bis(β-aminoenones) via amination of fluorinated 1,3-diketones with o-phenylenediamine in the presence of trialkyl borates was developed. Ni(II), Cu(II) and Pd(II) complexes with tetradentate bis(β-aminoenones) were obtained. Their gaschromatographic behaviour and main fragmentation paths in the electron ionization mass spectra were described.
Keywords :
complexes , Gas-chromatography–mass-spectrometry , amination , Fluorinated ligands
Journal title :
Journal of Fluorine Chemistry
Journal title :
Journal of Fluorine Chemistry
