Author/Authors :
Chen، نويسنده , , Guanlong and Chen، نويسنده , , Fuli and Zhang، نويسنده , , Yan and Yang، نويسنده , , Xueyan and Yuan، نويسنده , , Xiaoming and Wu، نويسنده , , Fanhong and Yang، نويسنده , , Xianjin، نويسنده ,
Abstract :
This paper studied the fluorination reaction of p-substituted benzenesulfonimides with diluted elemental fluorine to synthesize N-fluoro-benzenesulfonimide (NFSI) analogues. Several synthetic methods were compared and we found that, for many p-substituted benzenesulfonimides, the fluorination of their sodium salts with 10% F2–N2 mixed gas in acetonitrile at room temperature could afford NFSI analogues in moderate to good yields.