Title of article
α,α-Difluoro-α-phenylsulfanyl-α-trimethylsilylmethane as “CF2−” synthetic building block for the preparation of gem-difluoromethylenated cyclopentanols
Author/Authors
Peewasan، نويسنده , , Krisana and Kuhakarn، نويسنده , , Chutima and Soorukram، نويسنده , , Darunee and Tuchinda، نويسنده , , Patoomratana and Reutrakul، نويسنده , , Vichai and Pohmakotr، نويسنده , , Manat، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
367
To page
372
Abstract
A general strategy for the preparation of gem-difluoromethylenated cyclopentanols has been demonstrated; it involves sequential fluoride-catalyzed nucleophilic addition of α,α-difluoro-α-phenylsulfanyl-α-trimethylsilylmethane (PhSCF2SiMe3; 1) to homoallyl ketones followed by intramolecular radical cyclization.
Keywords
? , radical cyclization , ?-Difluoro-?-phenylsulfanyl-?-trimethylsilylmethane , gem-Difluoromethylenated cyclopentanols
Journal title
Journal of Fluorine Chemistry
Serial Year
2012
Journal title
Journal of Fluorine Chemistry
Record number
1611769
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