Title of article
Deoxofluorination Reactions Using N,N-Disubstituted Aminodifluorosulfinium Tetrafluoroborate Salts
Author/Authors
Mahé، نويسنده , , Olivier and L’Heureux، نويسنده , , Alexandre and Couturier، نويسنده , , Michel and Bennett، نويسنده , , Christopher and Clayton، نويسنده , , Simon and Tovell، نويسنده , , David and Beaulieu، نويسنده , , Francis and Paquin، نويسنده , , Jean-François، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
57
To page
60
Abstract
The synthesis of N,N-disubstituted aminodifluorosulfinium tetrafluoroborate salts is reported, and their behavior as deoxofluorinating agent was evaluated. The deoxofluorination reactions were performed using a primary alcohol, a secondary alcohol and a ketone. Results show that subtle modification of the structure of the reagents can noticeably affect the reactivity and the selectivity in deoxofluorination reactions.
Keywords
Alkyl fluoride , elimination , Fluoroalkene , Aminodifluorosulfinium salts , Deoxofluorination
Journal title
Journal of Fluorine Chemistry
Serial Year
2013
Journal title
Journal of Fluorine Chemistry
Record number
1612066
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